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・ Manganese deficiency
・ Manganese deficiency (medicine)
・ Manganese deficiency (plant)
・ Manganese dioxide
・ Manganese diselenide
・ Manganese fluoride
・ Manganese heptoxide
・ Manganese Mines
・ Manganese nodule
・ Manganese oxide
・ Manganese peroxidase
・ Manganese violet
・ Manganese(II) acetate
・ Manganese(II) bromide
・ Manganese(II) carbonate
Manganese(II) chloride
・ Manganese(II) fluoride
・ Manganese(II) iodide
・ Manganese(II) molybdate
・ Manganese(II) nitrate
・ Manganese(II) oxide
・ Manganese(II) phosphate
・ Manganese(II) phthalocyanine
・ Manganese(II) selenide
・ Manganese(II) sulfate
・ Manganese(II) sulfide
・ Manganese(II) telluride
・ Manganese(II) titanate
・ Manganese(II,III) oxide
・ Manganese(III) acetate


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Manganese(II) chloride : ウィキペディア英語版
Manganese(II) chloride

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Manganese(II) chloride describes a series of compounds with the formula MnCl2(H2O)x, where the value of x can be 0, 2, or 4. The tetrahydrate is the most common form of "manganese(II) chloride" and is represented by the formula MnCl2·4H2O, but the anhydrous form and dihydrate MnCl2·2H2O are also known. Like many Mn(II) species, these salts are pink, with the paleness of the color being characteristic of transition metal complexes with high spin d5 configurations.〔N. N. Greenwood, A. Earnshaw, ''Chemistry of the Elements'', 2nd ed., Butterworth-Heinemann, Oxford, UK, 1997.〕
==Preparation==
Manganese chloride is produced by treating manganese(IV) oxide with concentrated hydrochloric acid.
:MnO2 + 4 HCl → MnCl2 + 2 H2O + Cl2
This reaction was once used for the manufacture of chlorine. By carefully neutralizing the resulting solution with MnCO3, one can selectively precipitate iron salts, which are common impurities in manganese dioxide.〔.〕
In the laboratory, manganese chloride can be prepared by treating manganese metal or manganese(II) carbonate and hydrochloric acid:
:Mn + 2 HCl → MnCl2 + H2
:MnCO3 + 2 HCl → MnCl2 + H2O + CO2

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